赵晓明 教授 博士生导师 研究方向：有机氟化学、不对称催化及材料化 国内外学术组织任职情况（国内外学术组织名称）：2010年入选上海市“浦江人才”。 简介 课题组成员： List of publications： Synthesis of carbonyl 2-amino-pyrimidines via tandem regioselective heterocyclization of 1,3-diynes with guanidine and selective oxidation, Liang Zhang, Mingzhu Zhang and Xiaoming Zhao*,Chem. Commun., 2015, 51, 9370-9373. Regioselective formation of 2,4,5-trisubstituted oxazoles through transition-Metal free heterocyclization of 1,3-diynes with N,O-bis(trimethylsiyl)acetamide, Liang Zhang and Xiaoming Zhao*,Organic Letters, 2015, 17, 184-186. Enantioselective transformation of Na2SO3 into allylic sulfonic acids under Pd catalysis , Wei Liu, Xiaoming Zhao*, Hong-bo Zhang, Liang Zhang,Chem. Commun., 2015, 51, 655-657. Synthesis of allyl carbamates via regioselective domino reaction of amines, CO2 and unsymmetrical allyl chlorides under Pd catalysis, Juewang Cai, Min Zhang, Xiaoming Zhao* ,Eur. J. Org. Chem., 2015, 15, 5925-5928. Enantioselective synthesis of monofluorinated allylic compounds: Pd-catalyzed asymmetric allylations of dimethyl 2-fluoromalonate using new N-sulfinyl-based ligands, Ning Gao, Xiao-Ming Zhao*, Cheng-Si Cai and Jue-Wang Cai, Org. Biomol. Chem., 2015, 13, 9551-9558 (IF 3.57). Synthesis of allylic sulfonic acids via regioselective Pd-catalyzed allylic substitutions of Na2SO3,Wei Liu, Xiaoming Zhao*, Tetrahedron Lett., 2015, 56, 6800-6802. Enantioselective transformation of allyl carbonates into branched allyl carbamates using amines and recycling CO2 under iridium catalysis, Shengcai Zheng, Min Zhang, and Xiaoming Zhao*,Chem. -Eur. J., 2014, 20, 7216-7221. Enantioselective domino reaction of CO2, amine and allyl chloride under iridium catalysis: formation of allyl carbamates, Min Zhang, Xiaoming Zhao*, Shengcai Zheng,Chem.Commun., 2014, 50, 4455-4458. Asymmetric Synthesis of Allylic Sulfonic Acids: Enantio- and Regioselective Iridium-Catalyzed Allylations of Na2SO3, Wei Liu, Xiaoming Zhao*, Hongbo Zhang, Mingzhu Zhao,Chem. -Eur. J., 2014, 20, 16873-16876（highlighted by both a Frontispiece paper in Chem.-Eur.J. and by ChemViews）. Carbon-phosphor bond formation via enantioselective Pd-catalyzed allylations of diphenylphosphine oxide, Liang Zhang，Wei Liu and Xiaoming Zhao*,Eur. J. Org. Chem., 2014, 14, 6846-6849. Transition metal free heterocyclization of 1,3-diynes, nitriles and aqueous potassium hydroxide: synthesis of (E)-2,4,5-trisubstituted-(prop-1-enyl)oxazoles,Ling Ming, Jialiang Tang and Xiaoming Zhao*, Synthesis of chiral allylic thioesters: enantio- and regioselective iridium-catalyzed allylations of KSAc, Ning Gao and Xiaoming Zhao*,Eur. J. Org. Chem., 2013, 13, 2708-2714. Sulfur heterocyclization and 1,3-migration of silicon of 1,3-diynes with NaSSiPri3: One-pot synthesis of 2,5-disubstituted-3-triisopropylsilylthiophenes,Jialiang Tang, Ling Ming, and Xiaoming Zhao*,Synthesis, 2013, 45, 1713-1718. Carbon-Sulfur Bond Formation via Metal-Catalyzed Allylations of Sulfur Nucleophiles, Highly regioselective iridium-catalyzed and samarium-promoted coupling of allylic carbonates with ketones: New approach toward homoallylic alcohols,Wei Liu, Liang Zhang, Weikang Yang, and Xiaoming Zhao*,RSC Advances, 2013, 3, 19917-19919. Iridium-catalyzed enantioselective allylation of sodium 2-aminobenzenethiolate: an access to chiral benzo-fused N, S-heterocycles,Ning Gao, Xinwen Guo, Shengcai Zheng, Weikang Yang, Xiaoming Zhao*,Tetrahedron, 2012, 68, 9413-9418 (This paper was highlighted in Synfacts, 2013, 1, 71). Enantioselective Iridium-catalyzed allylation of sodium benzotriazolide: an efficient way to chiral allylbenzotriazoles,Min Zhang, Xinwen Guo, Shengcai Zheng, Xiaoming Zhao*,Tetrahedron Letters, 2012, 53, 6995-6998. Synthesis of 2,5-disubstituted thiophenes via metal-free sulfur heterocyclization of 1,3-diynes with sodium hydrosulfide,Jialiang Tang, and Xiaoming Zhao*,RSC Advances, 2012, 2, 5488–5490. One pot iridium-catalyzed asymmetrical double allylaitons of sodium Sulfide: a fast and economic way to construct chiral C2-symmetric bis(1-substituted-allyl)sulfane,Shengcai Zheng, Weiqing Huang, Ning Gao, Ruimin Cui, Min Zhang, and Xiaoming Zhao*,Chem. Commun., 2011, 45, 6969-6971. Enantioselective Palladium-Catalyzed Allylic Substitution of Sodium Benzotriazoleide ,Wei Liu, Dazhi Zhang,Shengcai Zheng, Yinshuang Yue, Dongge Liu and Xiaoming Zhao*,Eur. J. Org. Chem., 2011, 6288-6293 (This paper was highlighted in Synfacts, 2012, 8, 188). Carbon-sulfur bond formaton via Iridium-catalyzed asymmetrical allylation of aliphatic thiols Ning Gao, Shengcai Zheng, Weikang Yang, and Xiaoming Zhao*,Organic Letters, 2011, 13, 1514-1516 (This paper was highlighted by Organic Chemistry Portal, 2011, Dec, see: www.organic-chemistry.org/abstracts/lit3/207.shtm). Iridium-Catalyzed Asymmetric Allylation of Sodium Triisopropylsilanethiolate: a New Way to Form Chiral Thiols,Weiqing Huang, Shengcai Zheng, Jialiang Tang, and Xiaoming Zhao*,Org. Biomol. Chem., 2011, 9, 7897-7903. Highly regioselective Pd-catalyzed allylic alkylation fluorobis(phenylsulfonyl)methane of Xiaoming Zhao*, Dongge Liu, Shengcai Zheng, Ning Gao,Tetrahedron Letters, 2011, 52, 665-667. Regio- and Enantioselective Iridium-Catalyzed Allylation of Thiophenol: Synthesis of Enantiopure Allyl Phenyl Sulfides Organic Letters, 2010, 12, 4454-4457 (This paper was highlighted in Synfacts, 2010, 12, 1400). Readily Prepared 3-Chloro-1-(phenylthio)propene, a Versatile Three-Carbon Annulating Agent,Taoping Liu, Xiaoming Zhao*, Long Lu, and Theodore Cohen* ,Organic Letters, 2009, 11, 4576-4579. Iridium-catalyzed Regio- and Enantioselective Allylic Alkylation of Fluorobis(phenylsulfonyl)methane Iridium-Catalyzed Reactions of Trifluoromethylated Compounds with Alkenes: A Csp3-H Bond Activation a to the Trifluoromethyl Group,Y. Guo; X. Zhao; D. Zhang; S-I. Murahashi ,Angew. Chem. Int. Ed., 2009, 48, 2047-2049. Efficient 1,4-addition of a-substituted fluoro(phenylsulfonyl)methane derivatives to a,b-unsaturated compounds,G. K. Surya Prakash,* Xiaoming Zhao, Sujith Chacko, Fang Wang, Habiba, Vaghoo, and George A. Olah*,Beil. J. Org. Chem., 2008, 4, No. 17. 2-Phenylthio-3-bromopropene, a Valuable Synthons, Easily Prepared by a Simple Rearrangement Wenbo Chen, Xiaoming Zhao,* Long Lu and T. Cohen*,Organic Letters, 2006, 8, 2807-2090. A Platinum Acetylide Polymer with Sterically Demanding Substituents: Effect of Aggregation on the Triplet Excited State,Xiaoming Zhao, Thomas Cardolaccia, Richard Farley, Khalil A. Abboud and Kirk S. Schanze.Inorganic Chemistry, 2005, 44, 2619-2627 (IF 3.3).Bis-silyl substituted ferrocenylenes, including dicyanovinyl electron-withdrawing groups, as potential non-linear optical materials
所学专业：有机化学
职称：高级
类别：研究人员
联系电话：65981376
Email：xmzhao08@tongji.edu.cn
专业方向：有机化学
办公室：原新闻中心205室&化学馆105室
The biographical sketch：
Xiao-Ming Zhao obtained his Ph.D. from Daliang University of Technology in 1995. Then, he did postdoctoral research at the University of Florida (UF) and University of Southern California (USC) in the group of Prof G.K.Prakash and Prof G.A.Olah. He is currently a professor in Tongji University at Shanghai. His research group’s interests were recognized by the award of a Thieme Chemistry Journal Award in 2012 and focus on reaction design, asymmetric synthesis and fluorine chemistry.
男，博士，2008年4月 经同济大学全球人才招聘进入同济工作，任教授、博士生导师。
毕业于大连理工大学。1998启留学美国八年。于佛罗里达大学、南加州大学(G.K.S. Prakash 教授和诺贝尔奖得主G.A. Olah 教授组) 做博士后、高级副研究员。1995-1998及2004-2006于中国科学院上海有机化学有机所博士后学习与工作，曾任副研究员。归国后，研究工作受到国际同行关注，应邀在国际化学期刊Synthesis （2013, 45, 2051-69）撰写综述，介绍所取得的研究成果。
个人奖励：
2010 年入选上海市“浦江人才”。
2012 年荣获国际 Thieme 化学期刊奖“Thieme Chemistry Journal Award 2012” 。
研究方向：
设计和发现新反应，并将其发展为有用的合成方法，用于目标分子(如药物，功能材料等)或天然产物的合成。有机氟化学包括:氟化试剂、氟化方法、含氟材料等研究。高附加值精细化学品如:医药、农药、染料中间体等的合成研究。有机材料化学如:液晶，非线性材料，荧光和磷光材料等。
科研： 主持国家“自然基金项目”、上海市“浦江人才项目”和“教委重大创新项目”等多项，以及与企业合作项目。
教学： 主讲本科生和研究生的双语《有机化学》、《现代有机化学》、《绿色化学》、《精细有机合成新方法》等课程。
博士生：郑生才（获2010“优秀研究生”奖、2011“陶氏化学”特等奖、2012“国家奖学金”）。
高宁（同济保送攻博，获2011“倪天增”奖、2012“优秀研究生奖”、2013“国家奖学金”）。
刘炜（获2012“和氏璧”奖、2013“优秀研究生奖”、2014“合氏璧奖”）。
张敏 （硕转博，获2013“和氏璧”奖）。
郑璞睿 （2014同济保送攻博）。
陈骥腾（2015同济保送攻博）。
硕士生：唐佳亮（获2012“光华奖”）。刘海征 （获2013“陶氏优秀奖”）。张亮（获2014“和氏璧奖”）。
发表的论文：
Synthesis, 2014, 46, in press, web released on Jun. 24, 2014.
Wei Liu and Xiaoming Zhao*,Synthesis, 2013, 45, 2051-2069 (Invited review).
Wenbo Liu, Shengcai Zheng, Hu He, Xiaoming Zhao*, Lixin Dai, and Shuli You *,Chem. Commun., 2009, 43, 6604-6606.
Xiaoming Zhao, Hemant Sharma, Francisco Cervantes-Lee and Keith H. Pannell, Gary J. Long, Ahmed M. Shahin,J. Organomet. Chem.2003, 686, 235-241 (IF 2.04).